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Phosphorus oxonitride (PON) is isoelectronic with SiO2 and may exhibit a similar broad spectrum of intriguing properties as silica. However, PON has only been sparsely investigated under high‐pressure conditions and there has been no evidence on a PON polymorph with a coordination number of P greater than 4. Herein, we report a post‐coesite (pc) PON polymorph exhibiting a stishovite‐related structure...
Metal nanoparticles (NPs) dispersed on a high‐surface‐area support are normally used as heterogeneous catalysts. Recent in situ experiments have shown that structure reconstruction of the NP occurs in real catalysis. However, the role played by supports in these processes is still unclear. Supports can be very important in real catalysis because of the new active sites at the perimeter interface between...
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