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Kern‐Schale‐Kristalle von porösen Materialien ermöglichen die synergistische Nutzung multipler Funktionalitäten, etwa indem man das Kernmaterial auf hohe Kapazität hin auswählt und die Schale auf gute Selektivität, oder durch die Wahl der Oberflächeneigenschaften. Bekannt waren bisher Gerüststrukturen, in der Zuschrift auf S. 11398 stellen nun T. Hasell, A. I. Cooper et al. aus porösen Molekülen gebildete...
The first examples of core–shell porous molecular crystals are described. The physical properties of the core–shell crystals, such as surface hydrophobicity, CO2 /CH4 selectivity, are controlled by the chemical composition of the shell. This shows that porous core–shell molecular crystals can exhibit synergistic properties that out‐perform materials built from the individual, constituent molecules.
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