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Suppressing the mobility of anionic species in polymer electrolytes (PEs) is essential for mitigating the concentration gradient and internal cell polarization, and thereby improving the stability and cycle life of rechargeable alkali metal batteries. Now, an ether‐functionalized anion (EFA) is used as a counter‐charge in a lithium salt. As the salt component in PEs, it achieves low anionic diffusivity...
Der Einfang negativer Ladungen in Polymerelektrolyten mit einem froschförmigen, Ether‐funktionalisierten Anion (EFA) wird von H. Zhang, J. Carrasco, M. Armand et al. in ihrer Zuschrift auf S. 12198 vorgestellt. Das Bis(trifluormethansulfonyl)imid‐Anion (TFSI), hier als Kaulquappe gezeigt, ist in einer Poly(ethylenoxid)‐Matrix (PEO) hoch mobil. Im Gegensatz dazu ermöglichen die Ethylenoxid‐„Beine”...
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