The front cover picture, designed by Verena A. Resch and Stefan Payer, illustrates creating three stereocenters in two steps: the regio‐ and stereoselective mono‐amination of a prochiral triketone followed by chemical reduction gave access to xenovenine, the venom of the ant species Solenopsis tennesseensis. Each enantiomer can be accessed by switching from an (S)‐ to an (R)‐selective biocatalyst in the asymmetric key step of the sequence. Details can be found in the Full Paper on pages 444–451 (S. E. Payer, J. H. Schrittwieser, B. Grischek, R. C. Simon, W. Kroutil, Adv. Synth. Catal. 2016, 358, 444–451; DOI: 10.1002/adsc.201500781). The authors acknowledge supported by the University of Graz for the printing of the cover picture.