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Many unique properties of C60-based materials stem from the fact that purely molecular properties survive in the solid state, adding a level of complexity to their description. As the molecules are only weakly bonded by Van der Waals interactions, the overlap between their electronic wave functions is small and narrow bands are formed. Because of the narrowness of these bands (typically 0.5 eV), these...
Many unique properties of C60-based materials stem from the fact that purely molecular properties survive in the solid state, adding a level of complexity to their description. As the molecules are only weakly bonded by Van der Waals interactions, the overlap between their electronic wave functions is small and narrow bands are formed. Because of the narrowness of these bands (typically 0.5 eV), these...
The challenge to develop tailor-made precursor molecules for silicon carbide has significantly intensified the progress in synthesis of organosilicon polymers. A critical overview is presented regarding useful synthesis routes towards such molecules with appropriate chemical composition as well as controllable architecture (metal condensation of halogenosilanes or silahalogenocarbons, disproportionation...
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