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The concepts of the absolute surface potential (ASP) ES of the (hkl) facet of a metal crystal with ES = ΔGs/zF directly related to the Gibbs surface energy ΔGS and with an equilibrium between (auto) adsorption of its own atoms on this facet of Nad and negative charged surface vacancies (NCSV). On this basis, the ASP scale is a scale of adsorption potentials with point defects—the NCSV and adatoms,...
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