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The kinetics of reaction of phenylnitroso oxide and a number of its para-substituted analogues (R = Me2N, MeO, Me, and Br) with tetracyanoethylene in acetonitrile at room temperature was studied using flash photolysis. It was established that nitroso oxides exhibited nucleophilic properties in this reaction, and the rate constants for the trans forms of these species in the above series changed by...
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