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This is the first report of the crystal structure of mukhinite, V-analogue clinozoisite, on the join Ca2Al3Si3O12(OH)–Ca2Al2V3+Si3O12(OH) synthesized at 1.5 GPa and 800 °C. The study was performed to clarify the distribution of V3+ among structurally independent octahedral M1, M2, and M3 sites, and the effect of V3+ on the crystal structure. Mukhinite and V3+-bearing clinozoisite in all run products...
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