The calibration of the photoelectric parameters is an important research topic. It can improve the quality of the UV communication transceiver during the development phase. In this paper, we propose four parameters in order to unify the test method. The calibration device of each parameter is introduced in detail. Lots of experiments are executed to test the performance of the calibration device and the model product in the laboratory. The results indicate that the calibration device has high stability and practicability. The calibration data of the model product provide the reliable data security for the check and accept.