The SnO 2 –Sb 2 O 5 –RuO 2 , α-PbO 2 and β-PbO 2 films were successfully deposited on Ti nets using thermal deposition and electrodeposition methods. It was found that the SnO 2 –Sb 2 O 5 –RuO 2 interlayer played a very important role in enhancing the PbO 2 films electrodeposition. The Ti/SnO 2 –Sb 2 O 5 –RuO 2 /α-PbO 2 /β-PbO 2 electrodes obtained were superior not only in electrochemical stability but also in activity for pollutants degradation. The lifetime reached 59h under the accelerated life test conditions at a current density of 4A/cm 2 in 0.5M H 2 SO 4 solution. The COD removal and average current efficiencies were about 94% and 53% for degrading 500mg/L phenol at a current density of 100A/m 2 , and about 82% and 25% for degrading 1mM 4-chlorophenol at 200A/m 2 .