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Superparamagnetic Fe3O4 supraparticles@MIL-100(Fe) core–shell nanostructure microspheres were successfully constructed by a facile step-by-step method. The polyacrylate formed in situ during the process of the preparation of Fe3O4 supraparticles not only acted as a stabilizer on the Fe3O4 nanoparticles surface, but also played a crucial role as a “bridge” in the initial stage of the framework components...
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