The objective of this study was to establish the kinetic of reactions involved in redox cycles of an oxygen carrier material based on a perovskite type structure with the formula CaMg 0.1 Ti 0.125 Mn 0.775 O 2.9− δ . The oxygen transport capacity and reactivity of this material during reduction with gaseous fuels (CH 4 , H 2 and CO) and the subsequent oxidation with oxygen are studied in a TGA apparatus. Besides, the oxygen uncoupling properties of this material are analysed. Thus, kinetics for relevant reactions involved in Chemical Looping Combustion (CLC) and Chemical Looping with Oxygen Uncoupling (CLOU) were determined.CaMg 0.1 Ti 0.125 Mn 0.775 O 2.9− δ reactivity increased with the number of redox cycles, whereas the total oxygen transport capacity decreased from 8.5 to 8.0wt.%. Particles that reached the maximum reactivity were denoted as “activated” material. Kinetics for both fresh and “activated” particles was determined. Conversion vs. time curves at different temperatures (973–1273K), and reacting gas concentration (5–60vol.% for CH 4 , H 2 or CO; 5–21vol.% for O 2 ) were obtained for both fresh and “activated” material. For kinetics determination, the shrinking core model with control by chemical reaction and diffusion through the product layer was used to obtain the kinetic parameters.