Organic bistable light-emitting devices (OBLEDs) with an aluminum (Al)-nanoparticle-embedded tris(8-hydroxyquinoline)aluminum (Alq3) layer and double emitting layers (EMLs) were fabricated to investigate their color switching behaviors. Scanning electron microscopy images showed that Al nanoparticles were formed on the Alq3 layer. The Al nanoparticles in the Alq3 layer improved the storage margin of the organic bistable devices (OBDs), and the double EMLs changed the emission color of the organic light-emitting devices (OLEDs) according to the variations of the ON and the OFF states of the OBDs. The variations of the ON and the OFF states of the OBDs could be clearly distinguished by the color switching of the OLED. The luminances of the OBLEDs with double EMLs in the ON and the OFF states were 641.80 and 22.25 cd/m2, respectively, and their CIE coordinates at 20 V were (0.42, 0.46) and (0.51, 0.47), respectively, which corresponded to the ON and the OFF states of the OBLEDs.