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The electrochemical behaviour of triphenylstibine-containing Fischer carbene complexes of Mo(0) of the type [(SbPh3)(CO)4MoC(OEt)(Ar)] with Ar=2-thienyl (1), 2-furyl (2), 2-(N-methyl)pyrrolyl (3) or 2,2'-bithienyl (4) is reported. Results are compared to the related complexes [(L,L')(CO)3MoC(OEt)(Ar)] where L,L'=CO,CO; PPh3,CO; AsPh3,CO; or dppe (1,2-bis(diphenylphosphino)ethane). Linear trends and...
We systematically investigated the tuning of the reduction potentials (E0) for the first row transition metal (M=Cr, Mn, Fe, Co, Ni) complexes with the functionalized 1,4,7-Triazacyclononane-N,N',N”-triacetate (TCTA) ligands by means of DFT calculations. To predict reliable E0, the modified UB3LYP functional and equilibrium concept between high and low spin states were utilized. The functional groups...
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