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Radical reactions have been a fascinating arena in organic chemistry for decades and the rapid progress in this field is the topic of this review. Generation of radicals through sustainable catalysis using photoredox catalysts and iron based catalysts have significantly expanded the scope of radical reactions for carbon–carbon and carbon-heteroatom bond formations in recent years. Selective transformations...
A new nitrosation and oxidation process to synthesize gem-dinitro compounds was accomplished by using nitryl chloride as nitrosation reagent and ozone as oxidizing agent. The main features of the present protocol include the compatibility to substances with high steric hindrance, high yields and mild reaction conditions. A plausible mechanism involving the formation of an intermediate of gem-nitrosonitro...
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