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The isothermal crystallization behaviors of poly(bisphenol A-co-decane ether) (BA-C10) at different temperatures were studied in situ by means of Fourier transform infrared spectroscopic (FT-IR) measurements. Conformational changes during the induction period were investigated in details. The results suggest that conformational changes of polymer chains always take place before the start of changes in the characteristic FT-IR peaks of the crystalline phase.
State Key Laboratory of Polymer Physics and Chemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People's Republic of China
State Key Laboratory of Polymer Physics and Chemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People's Republic of China
State Key Laboratory of Polymer Physics and Chemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People's Republic of China
State Key Laboratory of Polymer Physics and Chemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People's Republic of China