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The results of measurements and analysis of excitation spectra of the λ lum =2350Ǻ luminescence corresponding to I 2 (D0 +u →X0 +g ) transition as well as luminescence at λ lum =3400Ǻ, where I 2 (D’2 g →A’2 u and/or β1 g →A1 u ) transitions occur, observed after three-step, λ 1 +λ f +λ 1 ...
Two-dimensional interaction potential energy surfaces for the ground-state ThO complexes with RG atoms from He to Ar are calculated ab initio at the coupled cluster CCSD(T) level of theory. The global minimum for all complexes is related to a bent geometry, with the RG atom closer to the oxygen end. Parallel symmetry adapted perturbation theory (SAPT) calculations for the ThO–He complex showed that...
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