The CO 2 permeation of composite membranes obtained by impregnation of molten alkaline carbonates into a Gd-doped ceria ceramic skeleton was tested using several gas mixtures with up to 50vol% CO 2 as feed gas and Ar in the membrane permeate side. Experiments performed in the 550–850°C temperature range showed high permeation rates reaching 0.6cm −3 min −1 cm −2 at 850°C for the higher CO 2 content. These values exceed those often reported for similar membranes and conditions. Furthermore, the characterization of the ceramic skeletons and composite membranes by impedance spectroscopy (in air at low temperature) could be used to estimate the temperature where dual oxide and carbonate ionic transport are balanced (around 800°C). The inherent shift in the CO 2 permeation activation energy is shown to match closely this prediction.