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Several Cu-MOFs were showed to be efficient heterogeneous catalysts for ortho-amination of benzoic acid derivative C–H bonds by N–H amines using 8-aminoquinoline as bidentate directing group. The optimal reaction conditions involve the use of Cu-MOFs (25%), N-methylmorpholine oxide (NMO) as an oxidant, secondary or primary amine coupling partner, DMF, DMA, or NMP solvent at 90–100°C. Furthermore,...
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