Through Pd catalyzed CN coupling reaction, Pd nanoparticles and diadamantylphosphine ligand were immobilized in situ into the formed N contained polymers as heterogeneous Pd catalysts for Suzuki-Miyaura reaction. The Pd@NPad2-1.0 catalyst was found to be highly efficient and only 4ppm of Pd (Pd@NPad2-1.0) was required for the coupling of aryl bromides with phenylboronic acid, and the corresponding...
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