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2-Chloro-2,2-difluoroacetamide has been studied by electron diffraction (ED) and ab initio Hartree–Fock (HF) calculations with 6-31G* and 6-311++G** basis sets and DFT calculation with a 6-311++G** basis set. The ab initio calculations predict one conformation with the C–Cl bond approximately orthogonal to the CCON skeleton and a slightly nonplanar NH2 group.Two different methods for calculation of...
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