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Two sulfonium salts of 1,4-anhydro-4-thio-d-galactitol, with structures related to the known sulfonium salt glycosidase inhibitor, salacinol, have been synthesized as potential inhibitors of UDP-galactopyranose mutase. The synthetic strategy relies on the alkylation reaction of 1,4-anhydro-2,3,5,6-tetra-O-benzyl-4-thio-d-galactitol at the sulfur atom with 2,4-O-benzylidene-d- or -l-erythritol-1,3-cyclic...
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