Ti3+ self-doped mesoporous black TiO2/SiO2/g-C3N4 sheets heterojunctions are successfully prepared by a sol-gel strategy, followed by calcination at 450 °C and hydrogenation at 500 °C. The characterization results indicate that Ti3+ self-doped mesoporous black TiO2/SiO2/g-C3N4 sheets heterojunctions photocatalysts possess high surface area of ∼145.6 m2 g−1, large pore size of ∼4 nm and pore volume of ∼0.27 cm3 g−1, respectively. The complete retention of the mesoporous frameworks is attributed to the addition of SiO2, which not only retards the growth of TiO2 crystals but also avoids the collapse of the channels even under high temperature calcination process. The prepared heterojunctions photocatalysts with narrow bandgap of ∼2.25 eV exhibit the excellent photocatalytic activity for degradation of phenol (98.5%), reduction of Cr6+ (97%) and photocatalytic hydrogen evolution (572.6 μmol h−1 g−1) under visible light irradiation, which is several times higher than that of pristine one. The outstanding photocatalytic property can be ascribed to the unique mesoporous framework enhancing the adsorption of pollutants and favoring the mass transfer, Ti3+ self-doping reducing the bandgap and extending the photoresponse to visible light region, the formation of heterojunctions preventing the recombination of photogenerated electrons and holes and benefiting their effective separation.