Composite membranes with a highly selective polymer skin for hydrogen separation

This study reports the fabrication of a highly hydrogen selective cross-linked polymer skin on a highly permeable mixed matrix membrane. Selective polymer skins were prepared by spin coating a thin layer of 6FDA-durene polymer onto ZIF-8/6FDA-durene mixed matrix membranes followed by subsequent cross-linking of the 6FDA-durene layer with ethylene diamine (EDA) vapor. Resultant membrane yielded significantly high gas pair selectivities for the separation of H₂/CO₂, H₂/N₂ and H₂/CH₄ of 29, 341, and 278, respectively, while also maintaining a high hydrogen permeability of 500Barrers. The superior separation performances of this system surpass the current permeability–selectivity tradeoff limits (Robeson 2008 upper bound) for H₂/CO₂, H₂/N₂, and H₂/CH₄ separations. The present work elucidates the potential of fabricating a highly selective layer (thin skin) on a highly permeable membrane to obtain high permeability and high selectivity simultaneously.