W/Fe-based components are considered as primary structural materials for the future fusion reactor. A five-layer W/Fe functional graded material (FGM) with W volume fraction of 0%, 25%, 50%, 75% and 100%, respectively, have been fabricated by a novel sintering method combining resistance sintering with ultra-high pressure. The sintering was carried out under pressures of 9GPa and an input power of 11kW for 60s. The microstructure of cross-section observed by SEM shows a well-graded transition. The relative density of each layer is more than 97%. A brittle phase Fe7W6 is formed at the interface of W particles and Fe particles, and this intermetallic phase coats Fe particles homogeneously with a thickness of 1–5μm. It is possible to avoid the brittle phase by choosing appropriate particle size and sintering parameters. In addition, Vickers hardness of W/Fe FGM was investigated before and after heat treatment.