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Trithiolato-bridged arene osmium complexes of the general formula [(p-cymene)2Os2(μ-SR)3]+ (R=C6H5, [1]+; C6H4-p-Me, [2]+; C6H4-p-OMe, [3]+; C6H4-p-Pri, [4]+; C6H4-p-But, [5]+; CH2C6H5, [6]+; CH2CH2C6H5, [7]+; CH2C6H4-p-But, [8]+) were synthesized in ethanol by reacting the p-cymene osmium dimer [(p-cymene)2Os2(μ-Cl)2Cl2] with the corresponding thiol (RSH). The complexes were isolated as their chloride...
Water soluble arene-functionalised trithiolato-bridged ruthenium complexes of general formula [(η6-C6H5OCH2CH2OH)2Ru2(μ-SR)3]+, where R=C6H5 (1), C6H4-p-Me (2), C6H4-p-OMe (3), C6H4-p-Pri (4), C6H4-p-But (5), CH2C6H5 (6), CH2CH2C6H5 (7) and CH2C6H4-p-But (8), were prepared from the reaction of [(η6-C6H5OCH2CH2OH)2Ru2(μ-Cl)2Cl2] with the corresponding thiol, RSH. Complexes [1]Cl–[8]Cl were isolated...
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