Polar Hexagonal Tungsten Oxide (HTO) Materials: (1) Synthesis, Characterization, Functional Properties, and Structure−Property Relationships in A 2 (MoO 3 ) 3 (SeO 3 ) (A = Rb + and Tl + ) and (2) Classification, Structural Distortions, and Second-Harmonic Generating Properties of Known Polar HTOs