In this work, a design equation was presented for a batch-recirculated photoreactor composed of a packed bed reactor (PBR) with immobilised TiO2-P25 nanoparticle thin films on glass beads, and a continuous-flow stirred tank (CFST). The photoreactor was studied in order to remove C.I. Acid Orange 7 (AO7), a monoazo anionic dye from textile industry, by means of UV/TiO2 process. The effect of different operational parameters such as the initial concentration of contaminant, the volume of solution in CFST, the volumetric flow rate of liquid, and the power of light source in the removal efficiency were examined. A rate equation for the removal of AO7 is obtained by mathematical kinetic modelling. The results of reaction kinetic analysis indicate the conformity of removal kinetics with Langmuir-Hinshelwood model (kL-H = 0.74 mg L-1 min-1, Kads = 0.081 mg-1 L). The represented design equation obtained from mathematical kinetic modelling can properly predict the removal rate constant of the contaminant under different operational conditions (R2 = 0.963). Thus the calculated and experimental results are in good agreement with each other.
Al-Ekabi H., Serpone N., 1988. Kinetic studies in heterogeneous photocatalysis. 1. Photocatalytic degradation of chlorinated phenols in aerated aqueous solutions over TiO2 supported on a glass matrix. J. Phys. Chem., 92, 5726-5731. DOI: 10.1021/j100331a036.
Arabatzis I.M., Antonaraki S., Stergiopoulos T., Hiskia A., Papaconstantinou E., Bernard M.C., Falaras P., 2002. Preparation, characterization and photocatalytic activity of nanocrystalline thin film TiO2 catalysts towards 3,5- dichlorophenol degradation. J. Photochem. Photobiol. A, 149, 237-245. DOI: 10.1016/S1010-6030 (01) 00645-1.
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