The article presents the description of measurement methodology of moisture transport in unsaturated porous materials using Time Domain Reflectometry (TDR) technique on the example of measurement of capillary uptake phenomenon in the sample of autoclaved aerated concrete (AAC). In the paper there are presented basic principles of the TDR method as a technique applied in metrology, its potential for measurement of moisture in porous materials like soils and porous building materials. Second part of the article presents the experiment of capillary rise process in the sample of AAC. Within the experiment moisture content was monitored in the sample exposed on water influence. Monitoring was conducted using TDR FP/mts probes. Preparation of the measuring setup was presented in detail. The TDR readouts post-processing, graphical presentations of the obtained results, short discussion and comparison of TDR readouts to gravimetric measurement were also presented.