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The gas-phase reactions of FeCF +2 and CoCF +2 with selected linear and branched alkanes and olefins, and cyclic alkanes are studied by Fourier transform ion cyclotron resonance (FTICR) mass spectrometry. For reactions with alkanes, condensation and initial C-C insertion are dominant, in contrast to the C-H insertion and carbene-alkyl coupling of FeCH +2 and...
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