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The interaction of molecular hydrogen (H2) with the stoichiometric RuO2(110) surface was studied at various temperatures and coverages by high-resolution scanning tunneling microscopy (STM) and temperature-programmed reaction (TPR). Metastable, heterolytic H-pairs of dissociated H2 consisting of one H adsorbed on a surface Ru atom and the other H at an adjacent bridging O atom are identified. This...
The interaction of O 2 with reduced rutile TiO 2 (110)–(1×1) has been studied by means of scanning tunneling microscopy (STM), temperature-programmed desorption (TPD) and photoelectron spectroscopy (PES). It is found that the interaction of O 2 with TiO 2 (110) depends strongly on the reduction state of the TiO 2 (110) crystal. High-resolution STM studies revealed...
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