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High-pressure, vapor-phase, hydrodeoxygenation (HDO) reactions of dihydroeugenol (2-methoxy-4-propylphenol), as well as other phenolic, lignin-derived compounds, were investigated over a bimetallic platinum and molybdenum catalyst supported on multi-walled carbon nanotubes (5%Pt2.5%Mo/MWCNT). Hydrocarbons were obtained in 100% yield from dihydroeugenol, including 98% yield of the hydrocarbon propylcyclohexane...
Pretreatment temperature affects the activity of a RhRe/C catalyst for CO hydrogenolysis of 2-(hydroxymethyl)tetrahydropyran and for dehydration of fructose. Catalytic activities for both CO hydrogenolysis and dehydration were observed to decrease with an increase in pretreatment temperature from 393 to 723K, which coincides with a decrease in the number of sites quantified using NH 3 temperature-programmed...
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