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The preparation, spectroscopic characterization (NMR and IR spectroscopy), and solid‐state structures of tri(3‐pyridyl)‐ and tri(4‐pyridyl)phosphine chalcogenides (E = O, S, Se) as well as their ability to behave as ligands for ZnTPP (TPP = tetraphenylporphyrinate) moieties are reported. In the solid state, the compounds from this family are three‐bladed molecular propellers that crystallize as racemates...
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