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The thermodynamic properties of Ca–Bi alloys were determined by electromotive force (emf) measurements to assess the suitability of Ca–Bi electrodes for electrochemical energy storage applications. Emf was measured at ambient pressure as a function of temperature between 723K and 1173K using a Ca(s)|CaF 2 (s)|Ca(in Bi) cell for twenty different Ca–Bi alloys spanning the entire range of composition...
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