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Altes Wissen gilt immer noch: 1911 wies Wieland erstmals eine radikalische Umlagerung nach, indem er die Produkte der thermischen Zersetzung von Ph3COOCPh3 studierte. In ihrer Zuschrift auf S. 6118 ff. bestimmen K. U. Ingold et al. die Geschwindigkeitskonstante dieser Isomerisierung sowohl experimentell als auch durch DFT‐Rechnungen. Im Widerspruch zu früheren photochemischen Befunden untermauern...
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