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ESR and optical absorption measurements were performed for six-coordinate Fe(III) TPP-butyl peroxide complexes formed in the reaction system composed of Fe(III) TPPCl, NaOCH 3 and t- or n-butyl hydroperoxide. The presence of four paramagnetic iron complexes was detected in the reaction system. Based on the spectroscopic parameters, the spin state and the axial ligand of these species were...
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