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Ethene was copolymerized with N,N-bis(trimethylsilyl)-1-amino-10-undecene in the presence of homogeneous, MAO-activated rac-Me 2 Si(Benz[e]Ind) 2 ZrCl 2 to yield, upon hydrolysis of the silylated amines, short chain branched linear low density polyethylene (LLDPE) with pendent aminoalkyl groups. Aminofunctional LLDPEs were characterized by means of 1 H-n.m.r. FTi.r...
A polymerization reactor system was designed to monitor simultaneously total and individual polymerization rates of liquid and gaseous 1-olefin monomers. Key element of this system is the combination of mass-flow meters and heat flow calorimetry. Polymerization kinetics of propene-and 1-octene-homo-and copolymerizations using the homogeneous methylalumoxane-activated Cp 2 ZrCl 2 were...
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