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The complex Pt 2 (pop) 4-4 abstracts hydrogen atoms and electrons from DNA upon photolysis into the dσ * →pσ excited state (pop = P 2 O 5 H 2-2 ). In duplex DNA, the hydrogen atoms are abstracted from the 4 - and 5 - positions of the deoxyribose functionality, and electrons are abstracted by tunneling from the guanine nucleobase...
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