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Phosphonium poly(ionic liquid)s (PILs) have been studied as alternatives to more common ammonium and imidazolium PILs for potential transport and separation applications. This work characterizes the CO2, H2, N2, O2, CH4, and C2H4 single-gas permeability, diffusivity, solubility, and selectivity of free-standing films of poly([(tri-n-alkyl)vinylbenzylphosphonium][bis(trifluoromethylsulfonyl)imide])...
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