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Protein therapeutics are increasingly used to treat various diseases, yet they often suffer from short serum half‐lives. An emerging strategy to extend lifetime in vivo is to attach fatty acids onto proteins to increase their binding to human serum albumin (HSA). Herein, the genetic encoding of ϵ‐N‐heptanoyl‐l‐lysine (HepoK) is reported, which introduces a fatty‐acid‐containing amino acid into proteins...
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