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The objective of this work was to study the influence of changing the cation of the ionic liquid (IL) on gas solubility. For this purpose, the low-pressure solubility of carbon dioxide and of ethane in three ILs based on the bis{(trifluoromethyl)sulfonyl}imide anion ([NTf 2 ] − ) was determined experimentally. Solubility data is reported for 1-ethyl-3-methylimidazolium ([C 1 ...
The first thiazolium gold(III) compound that qualifies as an ionic liquid has been prepared and crystallographically characterized. Hydration of phenylacetylene with this compound as catalyst precursor in ionic liquids indicates that gold(III)-based ionic liquids could serve both as solvents and catalysts for organic transformations. The potential re-use of catalysts is an advantage achieved by recycling...
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