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A series of mono- and heterodinuclear macro-acyclic complexes of [ZnLCu(II)]2+ and [ZnLNi(II)]2+ were synthesized by a stepwise procedure. The phenol-based macro-acyclic dicompartmental ligands (L2−) possess contagious hexadentate (N4O2) and tetradentate (N2O2) coordination sites, where in the mononuclear complexes [ZnL(H+)2]2+ the latter site containing two alkyl-imine donor groups (ethyl or isopropyl)...
Two phenol-based unsymmetrical dinucleating macro-acyclic ligands (LH 2 ), which can contiguously accommodate two metal ions, one in a hexa-coordinate (N 4 O 2 ) site and the other in a tetra-coordinate (N 2 O 2 ) site, and their heterodinuclear complexes [ZnLM II ] 2+ , where M=Cu or Ni, were prepared using a stepwise method. One of the ligand...
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