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This paper describes a system that permits the computer-aided formulation of comprehensive primary mechanisms and simplified secondary mechanisms, coupled with the relevant thermochemical and kinetic data in the case of the gas-phase oxidation of alkanes and ethers. This system has been demonstrated by modeling the oxidation of n-butane at temperatures between 554 and 737 K, i.e., in the negative...
This is an experimental and theoretical study of the inhibiting effect of the addition of 1-5% (relative to the amount of methane) of CF 3 I on methane oxidation under the following conditions: equimolecular CH 4 -O 2 mixtures, temperature from 970 to 1150 K, total pressure 1 bar, space times ranging from 1 to 8 s corresponding to methane conversions of 1-80%. The main observed...
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