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The sintering of nanocrystals to form a bulk film is a promising route for the production of low cost Cu2ZnSn(S,Se)4 solar cells. However, very little is known about how the synthesis of the nanocrystals impacts the properties of the sintered film or the performance of the resulting photovoltaic device. Here, we present a study in which devices were made from NC inks with different reaction times...
We present a photoluminescence study of a high-throughput experiment in which nanocrystal inks of different composition are mixed to produce a continuous composition gradient. Using this technique we have produced films in which the cation ratios of a CZTSSe absorber layer are continuously varied laterally on the substrate. Here we report the compositional dependence of peak intensity, position, and...
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