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The enzyme 2,4′‐dihydroxyacetophenone dioxygenase (DAD) catalyses the conversion of 2,4′‐dihydroxyacetophenone to 4‐hydroxybenzoic acid and formic acid. This enzyme is a very unusual dioxygenase in that it cleaves a C—C bond in a substituent of the aromatic ring rather than within the ring itself. Whilst it has been shown that DAD is a tetramer in solution, the recently solved crystal structure of...
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