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The O-polysaccharides of bacterial lipopolysaccharides are in general regular, periodic polymers with diverse structures that contain, in many instances, comparatively rare monosaccharides. The oligosaccharides that constitute the repeating units of these polysaccharide antigens provide a demanding challenge in terms of glycoside synthesis, an objective which is particularly important since these...
The tether employed to covalently attach β-mannan disaccharide glycoconjugates influences the specificity of rabbit antibodies that protect against Candida albicans. Two glycoconjugates containing (1 → 2)-β-mannan disaccharides linked to chicken serum albumin (CSA) either via a structurally uniform or via a stereodiversified spacer were prepared and evaluated in immunization trials in mice and rabbits...
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