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In comparison with other chemistries, little has been reported on sulfur‐containing plasma polymers; reasons include low volatility or high toxicity of monomers. Here, we report on plasma polymerization of dimethyl sulfoxide, by itself and its co‐polymerization with 1,7‐octadiene to generate S‐containing plasma polymers. Results show dominance of SS, SH, and SC with small percentages of SO and...
The incorporation of oxygen into nitrogen-containing plasma deposited polymers was studied by X-ray Photoelectron Spectroscopy (XPS). As the oxygen content of the plasma polymer increased, the binding energy of the N 1s photoelectrons increased. Conversely, the binding energy of the O 1s photoelectrons was inversely proportional to the nitrogen content of the plasma polymer. The data from a large...
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