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Alle metastabilen und stabilen Phasen konnten mithilfe einer Kombination aus quantenchemischen Rechnungen und Untersuchungen zur Phasenbildung für die feste Lösung Arsen/Phosphor identifiziert werden; ferner wurden Reaktionspfade zur Phasenbildung und ‐umwandlung in situ bestimmt. Die Ergebnisse zeigen, dass orthorhombisches, schwarzes Arsen (o‐As), offensichtlich in reiner Form metastabil ist und...
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