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RhCl 2 (Cp*)(monodentate P-ligand)- and trans-PdCl 2 (monodentate P-ligand) 2 -type complexes (where the P-ligand is either a P-heterocyclic or a cyclopropane-based tertiary phosphine) have been used as catalyst precursors in hydroformylation and hydroalkoxycarbonylation reactions, respectively. The chemoselectivity of hydroformylation is excellent (higher than 99%) in all...
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