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Hierarchically porous materials play an important role in facilitating mass transport and improving efficiency of adsorption and separation processes. In this paper, a new strategy is proposed to realize a hierarchically porous metal‐organic framework ([Cu2(OH)(L)]·(DMF)0.8 (FJU‐11, H3L=3,5‐(4‐carboxybenzyloxy)benzoic acid, DMF=N,N‐dimethylformamide) via using semi‐rigid multi‐carboxylic acids. Interestingly,...
This paper is focused on investigation of coordination polymers constructed by Cu(II) and rigid pyridyl ligands, such as 4,4′‐bipyridyl‐1,2,4‐triazole (Hpytz) and 1,10‐phenanthroline (phen) from a mononuclear precursor [Cu(DMF)4(NCS)2] (1). As expected, the complex was self‐assembled with phen to form a 1D double‐stranded chain of [Cu(phen)(µ‐SCN)2]∞ (2), with Hpytz to form 1D zigzag chain of [Cu2...
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